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Birefringent Crystalsal
(a-BBO , YVO4)

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Birefringent Crystalsal

v YVO4
va-BBOnew1.gif (1512 bytes)
vCalcite Crystal


Yttrium Vanadate (YVO4) Crystal
              -----Special Crystal For Fiber Optics

Yvo41.JPG (15706 bytes)The yttrium orthovanadate (YVO4) is a positive uniaxial crystal grown with Czochralski method. It has good mechanical and physical properties and is ideal for optical polarizing components because of its wide transparency range and large birefringence. It is an excellent synthetic substitute for Calcite (CaCO3) and Rutile (TiO2) crystals in many applications including fiber optic isolators and circulators, beam displacers, Glan polarizers and other polarizing optics, etc.

Basic Properties of YVO4 crystals

Transparency Range
               high transmittance from 0.4 to 5
mm

Yvo4curve.JPG (15066 bytes)

      Transparency Curve of YVO4(Thickness=1mm)

Crystal Symmetry
               Zircon Tetragonal, space group D4h
Crystal Cell
               a=b=7.12 Å; c=6.29 Å
Density: 4.22 g/cm3
Hygroscopic Susceptibility: Non-hygroscopic
Thermal Expansion Coefficient
   
  aa = 4.43 x 10-6/K; ac = 11.37 x 10-6/K
Thermal Conductivity Coefficient
      
ïïC: 5.23 W/m/K; ^ C: 5.10 W/m/K
Crystal Class: Positive uniaxial with no=na=nb, ne=nc
Refractive Indices, Birefringence (Dn = ne - no) and Walk-off Angle at 45º (r):
           
  no = 1.9929, ne = 2.2154, Dn = 0.2225, r = 6.04º         at 0.63 mm
              no = 1.9500, ne = 2.1554,
Dn = 0.2054, r = 5.72º         at 1.30 mm
              no = 1.9447, ne = 2.1486,
Dn = 0.2039, r = 5.69º         at 1.55 mm
Sellmeier Equation (l in mm):
             
no2 = 3.77834 + 0.069736/(
l2 - 0.04724) - 0.0108133l2
              ne2 = 4.59905 + 0.110534/(
l2 - 0.04813) - 0.0122676l2
Thermal Optical Coefficient: dna/dT = 8.5x10-6/K; dnc/dT = 3.0x10-6/K

Comparation with other Birefringent crystals

tCompared to Calcite, YVO4 has better temperature stability and physical and mechnical properties. Calcite is hard to obtain high optical quality because of its low susceptibility to moisture and low hardness.
tCompared to Rutile (TiO2) which exhibits too high hardness, YVO4 is easier to be handled for optical surface processing that greatly reduces cost of fabrication, especially for batch production.
tCompared to LiNbO3, although they have similar mechanical and physical properties, YVO4 has more than three times larger birefringence, that makes your design more compact.

Applications of YVO4 Crystals

           Following drawings are the simple demonstrations of how the YVO4 crystals are used in Fiber Optic Isolator, Beam Displacers and Circulators.

P59.jpg (11301 bytes) P59(2).jpg (7747 bytes)

Circulator1.JPG (35837 bytes)


CASIX unique advantages:

lReliable OEM supplier: CASIX has the largest production line of YVO4 crystals in the world. We have capacity to fabricate up to 10,000 pieces of YVO4 components per month.
lStrong Technical Support: From crystals growth and fabrication to fiber optics design and applications, CASIX engineers always provide professional solution to customers. Come to CASIX, let our expertise serves you better.
lQuick Delivery: We offer a series of standard YVO4 components which are commonly used in fiber optics (see the next page). They are available off-the-shelf.
lSpecial Products: Custom-made YVO4 components are welcome.


1. Birefringent Wedges for Fiber-Optic Isolators

   Specifications

Isolator1.JPG (15665 bytes)

Aperture

1.0 x 1.0 mm2 to 2 x 2 mm2

Dimension tolerance

+/-0.05mm

Wedge Angle tolerance

+/-15%

Optical axis orientation

+/-0.5¡ã

Flatness

l/4 @ 632.8 nm

Surface Quality

20-10

AR-coating

R<0.2% @1550

Standard Size

P/N

Crystal

XL

Y

Z

q

f

AR@

BWG3055

YVO4

0.5mm

1.4mm

1.4mm

5¡ã

22.5¡ã

1550nm

BWG3085

YVO4

0.5mm

1.4mm

1.4mm

8¡ã

22.5¡ã

1550nm

BWG3053

YVO4

0.5mm

1.4mm

1.4mm

5¡ã

22.5¡ã

1310nm

BWG3083

YVO4

0.5mm

1.4mm

1.4mm

8¡ã

22.5¡ã

1310nm

Note: Other sizes and Coating are available upon request


2. YVO4 Beam Displacer

Specifications

Beam(1).JPG (19025 bytes)

Dimension tolerance: ¡À0.05 x ¡À0.05 x ¡À0.1mm

Optical axis orientation: +/-0.5¡ã

Parallelism: <15 arc sec

Perpendicularity: <10 arc min

Flatness: l /4 @ 632.8 nm

Surface Quality: 20-10

AR-coating: R<0.2% @ 1550 nm¡À 40 nm

Note: Other sizes and specifications are available upon request

Standard Size

P/N

Crystal

Size

q

f

d

AR@

PBD3070

YVO4

2.6x2.6x7mm

45¡ã

0¡ã

0.70mm

1550nm

PBD3100

YVO4

2.6x2.6x10mm

45¡ã

0¡ã

1.00mm

1550nm

PBD3120

YVO4

2.6x2.6x12mm

45¡ã

0¡ã

1.20mm

1550nm

PBD3150

YVO4

2.6x2.6x15mm

45¡ã

0¡ã

1.50mm 1550nm

PBD3075

YVO4

2.6x2.6x7mm

45¡ã

45¡ã

0.70mm

1550nm

PBD3105

YVO4

2.6x2.6x10mm

45¡ã

45¡ã

1.00mm

1550nm

PBD3125

YVO4

2.6x2.6x12mm

45¡ã

45¡ã

1.20mm

1550nm

PBD3155

YVO4

2.6x2.6x15mm

45¡ã

45¡ã

1.50mm

1550nm


Barium Borate (a-BBO) Crystal
                    ---- A New Birefringence Crystal

          High Temperature form BBO (a-BaB2O4) is a negative uniaxial crystal. It has large birefringence over the broad transparent range from 189 nm to 3500 nm. Recently, CASIX has succeeded in growing this crystal into large size. The physical, chemical, thermal and optical properties of a-BBO crystal are similar to those of b-BBO. However, the nonlinear optical properties of a-BBO crystal is vanished due to the centric symmetry with its crystal structure. It is not recommended to use for NLO processes.

       a -BBO is an excellent crystal to replace Calcite, TiO2, and LiNbO3, etc. in Glan-Taylor and Glan-Thompson polarizers as well as walk-off beam splitters, especially for high power and UV polarizer, due to its unique UV transparency, good mechanical properties and high damage threshold. CASIX manufactures and supplies Glan-Laser, Glan-Taylor, Glan-Thompson Polarizers and other beam displacers from high quality a-BBO crystals to replace Calcite in many applications, especially in UV and high power operations.

1. Basic Properties of a-BBO

Transparency Range:
     189 - 3500 nm, See Transparency Curve

alfa-bboCurve.JPG (15167 bytes)

Transparency Curve of a-BBO

Density: 3.85 g/cm3
Therm-Optic Coefficients:
                            dno/dT = - 9.3 x 10-6/oC
                            dne/dT = -16.6 x 10-6/oC
Damage Threshold
       at 1064 nm                     1 GW/cm2
       at 355    nm                500 MW/cm2
Optical Homogeneity:Dn » 10-6/cm
Mohs Hardness: 4.5
Hygroscopic Susceptibility:Low
Thermal Expansion Coefficients
        (in the range of 25oC
¨C 900oC)
aa= 4 x 10-6/K
ac= 36 x 10-6/K

Linear Absorption Coefficients: a <0.005 cm-1 from 300 nm to 2300 nm

Refractive Indices, Birefringence (Dn = ne - no) and Walk-off Angle at 45o (r):
            at 1.0642 µm      ne = 1.58462,    no = 1.65790
      Dn =-0.073282       r =-4.9532o
            at 0.5321 µm     ne = 1.60206,    no = 1.67755
      Dn =-0.075491       r =-5.0407o
            at 0.2660 µm      ne = 1.67190,    no = 1.76171      Dn =-0.089805        
r =-5.6926o

2. Specifications of a-BBO

Surface Quality

20/10 Scratch and Dig

Beam Deviation

<3 arc min.

Optical Axis Orientation

+/-0.5¡ã

Flatness

l/4 @ 632.8 nm

Transmission Wavefront Distortion

<l /2 @632.8 nm

AR-coating

R<0.5%


3. Applications of a-BBO

Prisms.JPG (14820 bytes)

Extinction Ratio: <5X10-6
Angular Field: 6.0o

Prisms1.JPG (15484 bytes)

Extinction Ratio: <5X10-6
Angular Field: 6.0o

Prisms2.JPG (14738 bytes)

Angular Field: >6.9º
Cutting Angle: 45º

Part No.

Wavelength Range
(nm)

Clear Aperture
fa(mm)

Outside Diameter
f
d(mm)

L(mm)

Glan-Taylor Prisms

PGT8208

200-270

f8

25.4

17.0

PGT8210

f10

25.4

18.5

PGT8215

f15

30.0

23.0

PGT8220

f20

38.0

27.0

PGT8308

400-700

f8

25.4

17.0

PGT8310

f10

25.4

18.5

PGT8315

f15

30.0

23.0

PGT8320

f20

38.0

27.0

PGT8608

700-3000

f8

25.4

17.0

PGT8610

f10

25.4

18.5

PGT8615

f15

30.0

23.0

PGT8620

f20

38.0

27.0

Glan-Laser Prisms

PGL8208

200-270

f8

25.4

30.6

PGL8210

f10

25.4

31.0

PGL8215

f15

30.0

38.6

PGL8220

f20

38.0

48.9

PGL8308

400-700

f8

25.4

25.0

PGL8310

f 10

25.4

26.0

PGL8315

f15

30.0

33.4

PGL8320

f20

38.0

41.7

PGL8608

700-3000

f8

25.4

24.7

PGL8610

f10

25.4

25.9

PGL8615

f15

30.0

33.0

PGL8620

f20

38.0

43.6

Rochon Prisms

Part No.

Beam Deviation
a

Clear Aperture
fa(mm)

Outside Diameter fd(mm)

L(mm)

PRH8008

8¡ã @ 1064 nm

8

25.4

17.2

PRH8010

10

25.4

19.2

PRH8015

15

30.0

24.2

PRH8020

20

38.0

29.2


Calcite Crystal

          Calcite is a negative uniaxial crystal that has high birefringence, wide spectral transmission and availability in reasonably sized rhombs. Although is a fairly soft crystal and is easily scratched, it is ideal material used as visible and near IR polarizers, such as Glan Taylor, Glan Thompson and Glan laser.

        'CASIX selects carefully the raw calcite crystals by inspecting them with a cw green laser beam. We have perfected a number of proprietary processes for cutting, grinding and polishing good quality optical surfaces for calcite prism. These skills are evident in the high quality of the finished components, and enable polarizers to be used with very high peak power lasers.

Basic Properties of Calcite crystals

Calcite curve.JPG (15240 bytes)

Transparency Curve of Calcite

Transparency Range: 350nm - 2300nm

Particle Shape: Crystalline Rhombihedral

Density: 2.7 g/cm3

Hygroscopic Susceptibility:
           low susceptibility to moisture

Mohs Hardness: 3

Thermal Expansion Coefficient
    aa =24.39 x 10-6/K;
ac = 5.68 x 10-6/K

Crystal Class
    negative uniaxial with no=na=nb, ne=nc

Refractive Indices, Birefringence (Dn = ne - no) and Walk-off Angle at 45¡ã (r):
    no = 1.6557,    ne = 1.4852,     
Dn = -0.1705,    r = 6.20¡ã    at 0.63 mm
    no = 1.6629,    ne = 1.4885,
    Dn = -0.1744,    r = 6.32¡ã      at 1.30 mm

Sellmeier Equation (l in mm):
     no2 = 2.69705 + 0.0192064/(
l2 - 0.01820) - 0.0151624l2
     ne2 = 2.18438 + 0.0087309/(
l2 - 0.01018) - 0.0024411l2

Specifications

Surface Quality

20/10 Scratch and Dig

Dimension tolerance

¡À 0.1mm

Beam Deviation

<3 arc min.

Optical axis orientation

+/-0.5¡ã

Flatness

l/4 @ 632.8 nm

Transmission wavefront distortion

<l /2 @632.8 nm

AR-coating

R<0.5%


Copyright  1998 CASIX, Inc. All rights reserved. Last Revised: May 19, 1999
Web Page maintained by : Contact@CASIX.com

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